Just to make sure - did you actually change it in the Member table by hand or the intended way, by using the CMS? As this happened immediately after changing the e-mailaddress, you could try changing it to another e-mailaddress, or reenter the current one, by typing it by hand - not pasting it in.
I've had problems like this in the past where a hyphen was replaced by a special character version (pasting fronm Word 
)
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